Ceramic fiber module is made of ceramic fiber blanket by folding and compressing. Currently, it gradually becomes the first choice for the thermal insulation of industrial furnace linings.

Ceramic fiber module has white color and regular size. It can be directly fixed to the anchor nail on the steel plate of the furnace shell. It has good insulation performance and can improve the integrity of the furnace. It simplifies and speeds up the construction of furnaces and promotes the masonry techniques of furnaces.

It has many advantages over the ceramic fiber blanket.
1) During installation, after releasing the tying, the folded blankets can generate a huge stress, which makes them crowded together tightly without gaps.
2) The flexibility of ceramic fiber blanket can compensate the deformation of the furnace shell and reduce the construction cost. At the same time, it can make up the gaps caused by the thermal changes of the different components.
3) Since it has light weight and low thermal capacity, it can significantly reduce the energy cost during the temperature operation.
4) Flexible ceramic fiber blanket can withstand external mechanical forces.
5) It has good resistance to thermal shock.
6) The ceramic fiber lining requires no drying and maintenance. It can be put into use immediately after the construction is completed.
7) It has stable chemical properties. It is not eroded by acids, bases, water, oil and vapor, except phosphoric acid, hydrofluoric acid and strong base.

It can be used for the furnace lining insulation in the petrochemical industry, metallurgical industry, ceramic industry, glass industry, heat treatment industry and other industries.

Zhengzhou Sunrise Refractory supplies various ceramic fiber products including ceramic fiber blanket, ceramic fiber board, ceramic fiber module, ceramic fiber vacuum formed shapes, calcium silicate board, ceramic millboard, ceramic fiber paper, ceramic fiber bulk, and ceramic fiber cloth tape, rope and yarn.

When selecting refractories for regenerator chambers serving natural gas fired furnaces producing soda lime glass, both the functions of the refractories and the operating conditions within the checkers should be taken into consideration.

As heat exchangers, checkers should have high thermal capacity and thermal conductivity. Basic refractories and fused cast refractories are the best solution.

However, refractory selection also depends on the operating conditions, while the operating conditions depend on the position. According to the temperature, checkers can be divided into four zones: Top zone (from the first row to 1,350℃), Mid zone (from 1,350℃ to 1,000℃), Condensation zone (from 1,000℃ to 700℃) and Lower zone (from 700℃ to rider arches).

Top Zone

High temperature and batches and dusts result in chemical attack and gradual corrosion of the basic refractory bricks. If refractories are magnesia bricks, the chemical attack is up to the CaO/SiO2 ratio in the waste gases. if the radio is low, forsterite (Mg2SiO4) will be formed, which results in fissures opening within the bricks. Subsequently, silica penetrates these fissures resulting in the familiar cubic breakdown of the upper checkers. If the CaO/SiO2 ratio in the waste gases is high, a liquid phase enters into the refractory causing deformation. The best solution is magnesia bricks with high Mg content, well developed MgO crystals and a direct bonded structure. Additionally, the refractories should have low iron to avoid FeO oxidation to Fe2O3 and vice versa (Fe2O3 reduction to FeO) with volume variations and resultant brick failure.

Fused cast refractories have no surface porosity thus they are resistant to the corrosive effects of waste gases and carryover and can be used in all the checker zones. Compared to sintered refractories they are more resistant to abrasion due to their dense and homogeneous structure thus they are suitable for the top zone where there is a strong carry-over. Fused cast alumina brick is recommended for its very limited glassy phase. No glassy phase means no exudation therefore no excessive bonding with carry-over thus minimizing the risk of blockages.

Mid Zone

This zone is protected by the top checker area and temperature level is lower, thus 96% MgO with low iron and fused cast AZS 33# are recommended.

Condensation Zone

This is another critical area. The waste gases contain alkaline sulphate and SO3 which will condense out in the 1,000-700℃ range. In presence of sodium sulphate, the predominance of Na2O or SO3 in the waste gases causes chemical attack. Periclase base refractories are not chemically attacked by sodium sulphate or sodium oxide but they strongly react with SO3 forming MgSO4 causing densification of the Structure.

The chemical attack, enhanced by the presence of vanadium pentoxide when using fuel oil, breaks up the refractory and the structure densification lowers thermal shock resistance. Viable substitutes for chrome bearing refractories, which have a high resistance to condensates but cannot be used for environmental reasons, are both the spinel (MgO·Al2O3) and refractories made by periclase (MgO) and zirconia (ZrO2) having good resistance against Na2O and SO3.

When firing with natural gas, since the SO3 quantity is low, basic refractories can be used. When fused cast material is used, fused cast AZS is recommended.

Low Zone

Super duty fire clay brick can be used in non severe working conditions. 90-92% magnesia brick is recommended when firing by natural gas. Fused cast AZS 33# is also used in this zone.

Light weight high alumina brick is an ideal insulating refractory, with advantages of high strength, low thermal conductivity, good insulation property and low price. For various industrial kilns & furnaces, it is a kind of essential refractory for energy saving and temperature preservation.

Light weight high alumina brick is also called high alumina insulating brick. It contains more than 48% Ai2O3 and mainly consists of mullite and glass phase or corundum. It is usually made of high bauxite and a small amount of clay. After the raw materials are grounded, it is made into mud. Then it is cast and molded and fired at 1300～1500℃. Sometimes industrial alumimum is used to replace bauxite. Inorganic matter is added as ignition loss substance in order to increase the porosity of the refractory.

It has such advantages as high porosity, good insulation effect, high mechanical intensity, small thermal conductivity and long service life. It has high cold crushing strengh,size precision and holds the most stable and lowest thermal conductivity of all insulating refractory bricks at present. Its maximum service temperature is 1350℃. Thermal efficiency and working condition can be improved, energy consumption can be lowered, productivity and significant economic results can be achieved.

It is characterized by low bulk density. The total weight of the furnace body and walls thickness can be reduced effectively.

It has found a wide application in ceramics tunnel kiln, roller kiln, shuttle kiln, coking furnaces of iron and steel industry and other thermal equipment. It is mainly used in lining and insulating layer of areas without strong erosion by high temperature melts. When in direct contact with flame, the surface contact temperature can not be higher than 1350℃.

Zhengzhou Sunrise is a refractory material supplier from China, offering high quality insulation bricks, including High Alumina Insulating Brick, Fire Clay Insulation Brick, Mullite Insulation Brick, Magnesium Silicate Insulation Board, etc..

The key to production of silica bricks is to select the raw materials and the firing process in which the degree of quartz transformation is suitable for the intended application.

The raw material for silica brick is quartz which must meet certain requirements. If refractoriness or thermal expansion are the main requirements, a quartz of high chemical purity must be selected. If volume stability is the main requirement, raw materials should have good transformation properties.

The chemical composition of quartz is important in its evaluation as a raw material, in particular the content of alumina and alkali, as these lower the melting point and considerably reduce the possibilities of application. In addition the firing behavior of the quartz must be taken into account.

After the raw materials have been crushed, ground and screened to the various grain fractions, they are mixed in predetermined proportions according to the required application properties. In most cases, mixers are used for mixing and special bonding agents. Generally around 2% lime water and some sulphite solution as a temporary binder, are added at the same time. The mixture is then processed on friction presses or hydraulic presses. Complicated shapes or those where short runs are required, are still rammed by hand.

After drying, silica bricks are fired at temperature of about 1450-1500℃. Because the transformation of the silica takes place suddenly, cooling must be carried out slowly, or the brick will crack. It is necessary to maintain a carefully planned time temperature cycle during firing. A strong, well bonded high quality silica brick can be obtained only after passing through critical temperature ranges. During firing, silica brick will have about 4% linear growth.

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Silica brick is one of the most widely used high temperature refractory materials. Silica brick is a light yellow refractory product made from silica rock that contain at least 90 percent SiO2. It is used primarily in coke ovens and glass furnaces. It is also used in other applications, such as glass tank walls, acid practice electric furnaces, tunnel kilns, and regenerators.

Silica is the main component of silica brick. It occurs in a variety of crystalline modifications, e.g. quartz, tridymite, and cristobalite and also as an under-cooled melt called quartz glass. The crystalline modifications each have a high and low temperature forms which can transform reversibly. The crystal structure of the individual SiO2 modifications can differ widely, so that distinct density changes occur during transformation. This is of great importance during heating and cooling because of the change in the volume.

Quartz requires the smallest volume and the quartz glass the largest. During firing above approximately 900 ℃, quartz transforms into the other modifications and melt completely at 1725℃. During slow cooling , reversible volume decreases take place which are a result of the spontaneous transformation of the crystal structure from the high to the low temperature modification. The reversible and irreversible volume effects can cause considerable stress within the refractory brick structure.

Any common silica brick having large non-transformed silica content is undesirable because it exhibits extraordinary expansion so as to impair stability of industrial furnace which employs such brick as the refractory. Therefore, the extent of transformation of silica is one of very important factors which have to be considered in designing an industrial furnace in regard to selection of material and evaluation of adequateness of the use of the selected material.

Silica brick provides a high temperature resistant and non-reactive lining. It is characterized with its good resistance to spalling at high temperatures. It also retains their rigidity, are lightweight, have a good resistance to most fluxes present in coke ovens, and offer high resistance to abrasion. It has a relatively long lifespan. It is also nonreactive with the melted glass whereas other refractories, such as magnesia brick, could discolor the final product.

Silica brick is used as a refractory in building and repairing industrial furnaces, such as coke ovens, hot blast stoves and glass furnaces. Silica brick crowns have been successfully used in glass furnaces for producing container, float glass, table-ware and TV panel glass. They have the attributes of a relatively long life, excellent insulation at a low cost, and limited defects as silica is the dominant oxide.

Refractories are the main materials used in the glass furnaces and have big influence on the service life of glass furnaces, the quality of glass, the energy consumption and the cost. The development of the manufacturing technology of glass greatly depends on the the development of refractory technology and improvement of the quality of refractories.

Glass is melt at more than 1600℃, so the refractories will suffer from corrosion during the manufacturing process. The corrosion resistance performance and corrosion rate of refractories determines the service life of glass furnaces. The larger the scale of glass furnaces is, the bigger the production capacity is. The quality and accuracy of refractories has direct influence on the scale of glass furnaces. The application of the oxygen-fuel technology and reduced pressure technology depends on the performance of refractories, since those technologies increase the concentration of alkali vapor and water vapor, make the refractories more serious and have more demanding performance on the performance of refractories. Since the corrosion of refractories can also cause glass defects such as stones, bubbles and stripes, the corrosion resistance performance has a big influence on the quality of glass.

According to the types of glass produced, the size and structure of furnaces, the quality of glass required and the production capacity, different refractories are selected. So far, refractories for the glass industry, especially the float glass furnaces, include fused cast refractories, silica bricks and magnesia refractories.

Fused Cast Refractories

Fused cast refractories are refractories made by melting the raw materials and then casting the melt into a mold. Fused cast refractories for glass furnaces mainly include fused cast AZS, fused cast alumina block and fused cast high zirconia block. Fused cast AZS and fused cast alumina block are the main refractories used in float glass furnaces, Electronic glass furnaces, household glass furnaces, and pharmaceutical glass furnaces. Besides glass contact areas, they are also used in demanding areas such as the beast wall and the crown.

Silica brick

Silica brick is a traditional refractory used in glass furnaces, especially in the crown and superstructure. The quality of glass furnaces will affect the normal operation and service life of glass furnaces.

Magnesia refractories

Magnesia refractories are alkali refractories, including fused cast magnesia brick, high pure magnesia brick, direct bonded magnesia chrome brick and magnesia zircon brick. Magnesia refractories are mainly used in the regenerator.

Zhengzhou Sunrise is a refractory material supplier from China, offering high quality refractory materials for glass furnaces, including fused cast AZS block, fused cast alumina block, fused cast high zirconia block, mullite brick, zircon brick, alumina bubble brick, magnesia brick, sillimanite brick, corundum brick, low porosity fireclay brick, high alumina brick, all kinds of glass furnace ramming masses, etc..

Silica brick belongs to acid refractories, mainly consisting of tridymite, cristobalite and a small amount of residual quartz and glass phase. It has good resistance to acid slags.

The raw material for silica brick production is silica. The silica has a high content of SiO2 and high refractoriness. The most harmful impurities are Al2O3, K2O, Na2O, etc. They can seriously reduce the refractoriness of the silica brick. Silica brick is made of silica containing more than 96% SiO2 , with addition of mineralizing agent (such as iron scales, lime) and binder (such as molasses, sulfite pulp waste), by kneading, shaping, drying and calcining.

Silica brick has a high softening temperature under load up to 1640 ~ 1670 ℃ and good volume stability in long term use. The mineralogical composition of silica brick mainly consists of tridymite and cristobalite, as well as a small amount of quartz and glass phase.

Tridymite, cristobalite and residual quartz has a big volume change due to crystal transformation at low temperatures. Therefore, the thermal stability of silica brick is poor at low temperatures. During the use, the silica brick should be heated and cooled slowly in order to avoid cracks. It should not be used in the furnaces that have rapid temperature change below 800℃.

The property and process of the silica brick is closely related to the crystal transformation of SiO2. Therefore, the true specific gravity is an important quality indicator of silica brick. Generally it should be under 2.38. For the high quality silica brick, it should be under 2.35. The low true specific gravity means the quantity of tridymite and cristobalite is high and the amount of residual quartz is small. Therefore, the residual linear expansion is small and the strength decreases.

SiO2 has seven crystalline variants and a amorphous variant. These variants can be divided into two categories. the first category include quartz, tridymite and cristobalite. Their crystal structure is very different and the transformation between them is very slow. The second category are subspecies of the variants above, α,β and γ. They have similar structures and can be transformed to each other quickly.

Zhengzhou Sunrise is a refractory material supplier from China, offering high quality refractory materials for glass furnaces, including fused cast AZS block, fused cast alumina block, fused cast high zirconia block, mullite brick, zircon brick, alumina bubble brick, magnesia brick, sillimanite brick, corundum brick, low porosity fireclay brick, high alumina brick, all kinds of glass furnace ramming masses, etc..

The regenerator is an important part of the glass furnace, not only deciding the lifelong of the furnace but also directly affecting the production process. The refractory selection of the regenerator are of great importance. It must be proper for both the functions of the refractories and the operating environment.

The regenerators comprise a succession of chambers forming a stack and recovering and restoring the heat in cycles. Checkers and internal separation walls function as heat exchangers, while crowns and external walls limit thermal losses. The main operating factors to be considered are temperature, repeated temperature cycling, airborne particulates, volatiles and load. Fuel and glass composition must also be taken into consideration when choosing the refractories.

A regenerator chamber is composed of a checker composed of an upper, middle and lower zone. As heat exchangers, checkers must have high thermal conductivity and good thermal shock resistance. Basic materials and fused cast refractories are the best choices. However, the operating conditions will be very different at different position within the chamber.

Fused cast refractories have no surface porosity thus they are resistant to the corrosive effects of waste gases and carryover and can be used in all the checker zones. Compared to sintered refractories they are more resistant to abrasion due to their dense and homogeneous structure.

In the upper zone of the checker, high temperature combined with batch carry over results in chemical attack and gradual degradation of the basic checkers. The atmosphere in the top zone is laden with alkali vapors. The refractories in this area must have low iron. The best choice is 97 magnesia brick, with well developed periclase crystals and a direct bonded structure. Fused cast alumina is also used for its very limited glassy phase.

The middle zone is protected by the upper checker area and temperature level is lower. The atmosphere is rich in alkali vapors, and some deposition of condensates occurs. Thus magnesia brick 96 is used. Fused cast AZS 33# can also be used. However, in term of costs, magnesia brick is a better choice.

In the lower zone, the temperature is lower, but the temperature cycles may be wide where cold incoming air enters the checker, under higher load and temperature fluctuations, with sulphuric salt erosion. Low porosity fireclay bricks or high alumina bricks can be used in non severe working conditions and 90-92 magnesia brick is recommended when firing by natural gas. Fused cast AZS 33# is also used in this zone.

The rider arches is subjected to high temperature chemical attacks by high temperature glass material dust, fuel impurities and alkaline steam. Refractories used here should have good resistance to erosion and high temperature. Traditionally high quality silica brick is used, but silica bricks have poor resistance to alkaline erosion. Sillimanite and mullite bricks are recommended. Fused AZS bricks can also be used.

Considering only creep resistance, silica brick is ideal because of its lack of glassy phase but condensation of alkali in the colder zones of the masonry would lead to corrosion, loss of mass and also holes of silica bricks. Mullite brick is also suitable for the crowns for its excellent creep resistance. Mullite bricks react with alkali and carryover to form a series of layers which prevent alkali penetrating into the bulk of the refractory and wear proceeds at a minimal rate.

The refractories used in the sidewalls and floor are usually selected from fireclay brick, high alumina brick, and silica brick.

The popular type of furnace used for the production of E glass is the unit furnace. More than 10 kinds of refractories are used to build to the furnace.

Fused cast AZS block

Fused cast AZS 33# is mainly used in the burner block of the melting zone and the feeder block.

Dense chromium oxide brick

Dense chromium oxide brick has the best resistance to the corrosion by E glass. It almost causes no pollution to the glass liquid. It is ideal for the E glass furnace. It is made by isostatic pressing. It has a very dense structure. It contains more than 94% Cr2O3 and less than 15% pores and its bulk density is 4.24g/cm3. Its erosion loss is only 1/10 of that of the dense zircon brick. It is mainly used in the high temperature glass-contact areas, such as the sidewall and the tank bottom of the melting zone and the sidewall of the main channel and transition channel.

Dense zircon brick

The resistance of Dense zircon brick to high temperature and E glass is not as good as dense chromium oxide brick. It is made by isostatic pressing too. It contains more than 65% ZrO2 and less than 2.0% pores and its bulk density is 4.25g/cm3. If the operating temperature exceeds 1370℃, it will be eroded. It is mainly used as the bottom block in the lower temperature parts of the melting zone and the forming channel and transition channel, flow block and back-up block.

Zircon brick

Zircon brick contains 66% ZrO2 and its bulk density is 3.7g/cm3. It has good thermal stability and good creep resistance. Its is the sidewall and breast wall of the feeder port where the erosion of batches is severe, peep hole and the breast wall, crown and burner of the flame space of the channel.

Sintered mullite brick

Sintered mullite brick contains more than 74% Al2O3;2.2% SiO2 and its bulk density is 2.5g/cm3. It is generally used as the back-up brick of the zircon brick, the breast wall and front wall of the melting zone, the lining brick of the flue of the channel, the foot parts of the crown and the outside layer of the discharging port

There is another type of mullite brick which is made by melting the raw materials first to form mullite crystals and then sintering it. It has better resistance to creep and thermal shock than mullite brick. It can be used in the crown and the breast wall of the flame space.

Fused cast mullite brick

Fused cast mullite brick is made of the bauxite, high quality alumina powder and clay by the fused cast method. It is mainly used in the flue.

Fused chrome corundum brick

Fused chrome corundum brick contains 28.3% Cr2O3, 58.3% Al2O3, and 5.2% MgO and Fe2O3. Its bulk density is 3.4g/cm3. It is used as the flue interface brick of the heat exchanger.

Besides the refractories mentioned above, difference types of fireclay brick and insulation brick are used in the outside layer of the furnace.

With the development of technology, a variety of zirconia refractories have been developed. Recently, zirconia refractory, as a new type of refractory, has been widely used in the metallurgy, construction and chemical industry.

ZrO2 is widely used in the refractory for the glass industry, metallurgy industry, construction industry and chemical industry, because it has high melting temperature, good thermal shock resistance and high chemical stability. Zirconia refractories are mainly used in demanding areas of glass furnaces such as the superstructure, the melting zone, the sidewall and the throat.

The main types of zirconia refractories include zircon bricks, dense zircon bricks, fused cast AZS block, fused cast zirconia mullite block and bonded again AZS bricks.

In the metallurgical industry, based on the materials, zirconia refractories can be divided into zirconite refractory, zirconia refractory, aluminum zirconium refractory, calcium zirconate refractory, zirconium diboride refractory and modified zirconia refractory.

Zirconite refractory features high temperature performance, good resistance to acid slags, good corrosion resistance, low thermal expansion coefficient and good thermal shock resistance. It can be used in the ling of the ladle.

The raw materials for zirconia refractories include zirconite refractories in various sizes and various zirconia materials. The molding methods include slurry casting method, machine pressing method and isostatic pressing method. Different molding methods have different requirements for the grains of raw materials. Products made in different methods have different performance and applications, but all have the feature of good resistance to high temperature and corrosion.

Aluminum zirconium refractory is developed based on the aluminum carbon refractory. It is mainly used in the ladle, tundish, slide gate brick, long nozzle, stopper and outlet. Compared to aluminum carbon refractory, it has better resistance to oxidation, thermal shock and corrosion, higher strength and longer service life.

Zhengzhou Sunrise is a refractory material supplier from China, offering high quality refractory materials for glass furnaces, including fused cast AZS block, fused cast alumina block, fused cast high zirconia block, mullite brick, zircon brick, alumina bubble brick, magnesia brick, sillimanite brick, corundum brick, low porosity fireclay brick, high alumina brick, all kinds of glass furnace ramming masses, etc..